Ransoming Muslim prisoners who have been captured by kaafirs is better than 
 freeing slaves, so it is included and indeed takes priority, because they 
 suffer great harm by being separated from their families and because of the 
 humiliation and torture. So saving them is even more important than saving 
 slaves.

Where Zakah is to Be Spent

Shaykh Ibn Jibreen

Eligibility for Zakaah

Is it permissible to ransom Muslim prisoners using zakaah money?

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